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Konieczkowska, Jolanta, 2023, "Kinetics of the dark cis-trans isomerization of azobenzene and azopyridine derivatives in ethanol and chloroform solutions", https://doi.org/10.18150/RYX5QS, RepOD, V1
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The study aimed to investigate the kinetics of dark cis-trans relaxation for a series of azobenzene (Az, alko-Az) and azo pyridine (AzPy-o, AzPy-m, AzPy-p, alko-AzPy-o, alko-AzPy-m, alko-AzPy-p) compounds containing OH- or 6-hydroxyalkoxyl group. Azo pyridines possess nitrogen atoms in ortho, meta, or para position relative to the N=N bond. The studies showed the effect of nitrogen atom's presence in the dye's structure and their localization on the kinetics of dark cis-trans reaction and the possibility of azo-hydrazone formation by hydroxy-substituted chromophores.
The data set includes files:
azobenzene, azopyridine, isomerization, DFT calculations
Jolanta Konieczkowska, Anna Wasiak, Anna Sobolewska, Stanisław Bartkiewicz, Jan G. Małecki, Ewa Schab-Balcerzak, Kinetics of the dark cis–trans isomerization of azobenzene and azo pyridine derivatives in ethanol and chloroform solutions, Journal of Photochemistry & Photobiology, A: Chemistry 444 (2023) 114979. https://doi.org/10.1016/j.jphotochem.2023.114979 doi: https://doi.org/10.1016/j.jphotochem.2023.114979
CC BY - Creative Commons Attribution 4.0
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