Kazimierz Wielki University in Bydgoszcz

This research focuses on LPE growth and the examination of the optical and photovoltaic properties of single crystalline film (SCF) phosphors based on Ce³⁺-doped Y₃Mg_xSi_yAl_5−x−yO₁₂ garnets with Mg and Si contents in x = 0–0.345 and y = 0–0.31 ranges. The absorbance, luminescence, scintillation, and photocurrent properties of Y₃Mg_xSi_yAl_5−x−yO₁₂:Ce SCFs were examined in comparison with the Y₃Al₅O₁₂:Ce (YAG:Ce) counterpart. Especially prepared YAG:Ce SCFs with a low (x, y < 0.1) concentration of Mg²⁺ and Mg²⁺–Si⁴⁺ codopants also showed a photocurrent that increased with rising Mg²⁺ and Si⁴⁺ concentrations. Mg²⁺ excess was systematically present in as-grown Y₃Mg_xSi_yAl_5−x−yO₁₂:Ce SCFs. The as-grown SCFs of these garnets under the excitation of α–particles had a low light yield (LY) and a fast scintillation response with a decay time in the ns range due to producing the Ce⁴⁺ ions as compensators for the Mg²⁺ excess. The Ce⁴⁺ dopant recharged to the Ce³⁺ state after SCF annealing at T > 1000 °C in a reducing atmosphere (95%N₂ + 5%H₂). Annealed SCF samples exhibited an LY of around 42% and scintillation decay kinetics similar to those of the YAG:Ce SCF counterpart. The photoluminescence studies of Y₃Mg_xSi_yAl_5−x−yO₁₂:Ce SCFs provide evidence for Ce³⁺ multicenter formation and an energy transfer between various Ce³⁺ multicenters. The Ce³⁺ multicenters possessed variable crystal field strengths in the nonequivalent dodecahedral sites of the garnet host due to the substitution of the octahedral positions by Mg²⁺ and the tetrahedral positions by Si⁴⁺. In comparison with YAG:Ce SCF, the Ce³⁺ luminescence spectra of Y₃Mg_xSi_yAl_5−x−yO₁₂:Ce SCFs greatly expanded in the red region. Using these beneficial trends of changes in the optical and photocurrent properties of Y₃Mg_xSi_yAl_5−x−yO₁₂:Ce garnets as a result of Mg²⁺ and Si⁴⁺ alloying, a new generation of SCF converters for white LEDs, photovoltaics, and scintillators could be developed.