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Bartosiewicz, Karol, 2024, "Modification of photoluminescence wavelength and decay constant of Cr:Gd3Ga5O12 substituted by Ca/Si cation pair", https://doi.org/10.18150/FRGADV, RepOD, V1
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In this study, the photoluminescence wavelength and decay constant of Cr:Gd3Ga5O12 garnet oxide were modified by substituting Gd3+/Ga3+ cations with a Ca2+/Si4+ cation pair. The primary objective of this study was to shift the emission wavelength to the near-infrared (NIR) region and accelerate decay of Cr:Gd3Ga5O12 for its potential use as a scintillation detector in medical applications. The incorporation of Ca2+ and Si4+ ions in site of Gd3+/Ga3+ ions resulted in a significant redshift in the photoluminescence wavelength of Cr3+ ions and an acceleration of decay. The results clearly demonstrated that Ca2+/Si4+ cation pair substitution is a clearly effective strategy for modulating the optical properties of Cr:Gd3Ga5O12, with the potential to develop a NIR garnet scintillator.
near infrared phosphors, garnets, phosphors, Gd3Ga5O12, Cr3+
Shimoyama, Natsuki & Kodama, Shohei & Bartosiewicz, Karol & Fujiwara, Chihaya & Yanase, Ikuo & Takeda, Hiroaki. (2024). Modification of photoluminescence wavelength and decay constant of Cr:Gd3Ga5O12 substituted by Ca/Si cation pair. Journal of the Ceramic Society of Japan. 132. 364-368. https://www.jstage.jst.go.jp/article/jcersj2/132/7/132_23216/_article doi: 10.2109/jcersj2.23216
CC BY - Creative Commons Attribution 4.0
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