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Calorimetric data of liquid Ag-Mg-Ti alloys

Version 1.0

Dębski, Adam, 2025, "Calorimetric data of liquid Ag-Mg-Ti alloys", https://doi.org/10.18150/YWRKBW, RepOD, V1

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Description

TXT files with column headers Index Time (h) Furnace Temperature (°C) Sample Temperature (°C) HeatFlow (µV). Calisto software version 1.39 (Setaram Instrumentation - KEP Technologies, Caluire, France) was used to measure thermal effects.

The calorimetric data for five separate experimental series, with constant ratios of xAg/xMg = 9/1, 7/3, 1/1, and 3/7, and xAg/xTi = 19/1.

Tab_2_Series_A.txt: 9/1 (xAg/xMg = 9/1);

Tab_2_Series_A_prim.txt: 9/1 (xAg/xMg = 9/1);

Tab_2_Series_B: 7/3 (xAg/xMg =7/3);

Tab_2_Series_C: 1/1 (xAg/xMg =1/1);

Tab_2_Series_D: 3/7 (xAg/xMg =3/7);

Tab_3_Series_E: 19/1 (xAg/xTi = 19/1.).

The measurements were performed using the drop calorimetry method at temperatures of 1294 K and 1297 K for the liquid solutions with the following constant mole fraction ratio: xAg/xMg = 9/1, 7/3, 1/1, 3/7 [(Ag0.9Mg0.1)1−xTix, (Ag0.7Mg0.3)1−xTix, (Ag0.5Mg0.5)1−xTix, (Ag0.3Mg0.7)1−xTix)], and xAg/xTi = 19/1 [(Ag0.95Ti0.05)1−xMgx].

The experimental studies of liquid Ag-Mg-Ti alloys can be used in the future to optimize thermodynamic properties and phase diagram calculations. The results of drop calorimetric measurements at 1294 K and 1297 K for liquid Ag-Mg-Ti alloys indicate that the liquid solutions exhibit negative deviations from ideal behavior. The minimum integral molar enthalpy value was -13.444 kJ/mol for alloy Ag0.95Ti0.05 and xMg = 0.4182.

Subject

Chemistry; Engineering; Physics; Other

Keyword

Ag–Mg–Ti; calorimetry; enthalpy of mixing; liquid alloys; magnesium alloys; thermodynamic modeling; thermodynamic properties

Related Publication

Gozdur, W.; Gąsior, W.; Zrobek, M.; Budziak, A.; Dębski, R.; Gierlotka, W.; Pęska, M.; Polański, M.; Dębski, A. Calorimetric Studies and Thermodynamic Modeling of Ag–Mg–Ti Liquid Alloys. Materials 2024, 17, 1786. https://doi.org/10.3390/ma17081786 https://doi.org/10.3390/ma17081786 doi: 10.3390/ma17081786

License

CC0 Creative Commons Zero 1.0

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		Tab_2_Series_A.txt Plain Text - 35.7 MB - Aug 29, 2025 - 0 Downloads MD5: 95b23fc50dda7ed12a1a451a471fe927 License: CC0 Creative Commons Zero 1.0	Preview Download
		Tab_2_Series_A_prim.txt Plain Text - 39.3 MB - Aug 29, 2025 - 0 Downloads MD5: de5172d7b1244d592d31c4b50018bc0b License: CC0 Creative Commons Zero 1.0	Preview Download
		Tab_2_Series_B.txt Plain Text - 49.4 MB - Aug 29, 2025 - 0 Downloads MD5: 734298e467361c0f0f24422ee4d06ad3 License: CC0 Creative Commons Zero 1.0	Preview Download
		Tab_2_Series_C.txt Plain Text - 47.1 MB - Aug 29, 2025 - 0 Downloads MD5: b282e9310f08f1d95ba58d2b39c41d12 License: CC0 Creative Commons Zero 1.0	Preview Download
		Tab_2_Series_D.txt Plain Text - 62.1 MB - Aug 29, 2025 - 0 Downloads MD5: e93863dc218f748f5aba54018d3e9fc0 License: CC0 Creative Commons Zero 1.0	Preview Download
		Tab_3_Series_E.txt Plain Text - 56.8 MB - Aug 29, 2025 - 0 Downloads MD5: 8efb0be2fe2a4a8eca16bb2a97bb75ca License: CC0 Creative Commons Zero 1.0	Preview Download

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