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Experimental verification of halomethyl carbinols synthesis from carbonyl compounds using a TiCl4-Mg bimetallic complex promoter

Version 1.0

Michalak, Olga; Żurawicka, Sylwia; Kubiszewski, Marek; Krzeczyński, Piotr; Leś, Andrzej; Filipek, Sławomir; Cybulski, Marcin, 2025, "Experimental verification of halomethyl carbinols synthesis from carbonyl compounds using a TiCl4-Mg bimetallic complex promoter", https://doi.org/10.18150/UA4KP0, RepOD, V1

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Description

Table of Content of Supporting Information (PDF) for the article:

[S.1] Modeling of the Mg powder and reagents

[S.2] Reaction of Mg powder with CH2Br2

[S.3] Reaction of Mg powder with Mg∷CH2Br2 complex and TiCl4

[S.4] A model of the reaction of the solvent molecules with the Ti/Mg catalyst.

[S.4.A] Inclusion of DBE to the TiCl3∷MgCH2Br2 bimetallic catalyst

[S.4.B] Inclusion of DEE to the TiCl3∷MgBr2 bimetallic catalyst

[S.4.C] Inclusion of 2,5-dihydrofuran to the TiCl3∷MgCH2Br2 bimetallic catalyst

[S.5] A model of 1,2-dichloroethane reaction with the magnesium powder

[S.6] A model of the reaction of benzaldehyde with Ti/Mg catalyst

[S.7] Hydrobenzoin formation promoted by the Ti/Mg catalyst

[S.8] A possible formation of 1-bromomethyl)benzyl alcohol

[S.9]A cumulative stoichiometric reaction of hydrobenzoin formation

[S.10] The solvent effect on the output of the reaction (E.5) in the main text

[S.11] NMR spectra

[S.12] HRMS and EA spectra


ZIP file contents:

  • separate figures and a table from PDF file.
(2024-10-09)
Subject
Chemistry
Keyword

chemical reactions, chemical structures, NMR spectra, HRMS spectra

Related Publication

O. Michalak, S. Żurawicka, M. Kubiszewski, P. Krzeczyński, A. Leś, S. Filipek, M. Cybulski. "Experimental verification of halomethyl carbinol synthesis from carbonyl compounds using a TiCl4-Mg bimetallic complex promoter", RSC Advances (2024) 14, 39609-39617. https://pubs.rsc.org/en/content/articlelanding/2024/ra/d4ra07250b doi: 10.1039/d4ra07250b

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Separate figures for PDF file.
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