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Raw Data for Confined Reactions under Light-Driven Monolayer Compaction

Version 1.0

Kravets, Mykola, 2026, "Raw Data for Confined Reactions under Light-Driven Monolayer Compaction", https://doi.org/10.18150/SDSH8E, RepOD, V1

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Description

This dataset contains NMR, UV–Vis, HRMS, DLS, and TEM data for small and large AzoMUS-functionalized gold nanoparticles (AzoMUS@AuNPs).

The NMR data document the synthesis and characterization of the AzoMUS ligand, determination of the pKa of S+ in the absence and presence of trans-AzoMUS@AuNPs and cis-AzoMUS@AuNPs, analysis of ligand desorption following iodine treatment of AzoMUS@AuNPs, and investigation of the complexation of S2+ with both nanoparticle photoisomers.

The UV–Vis data include kinetic studies of S+-long and S2+ in the presence of trans- and cis-AzoMUS@AuNPs, determination of the binding constants of S2+ with both nanoparticle forms, stoichiometry analysis of S2+-AzoMUS@AuNP complexes using Job plots, evaluation of activation parameters through Arrhenius and Eyring analyses, and calculation of Hill-derived occupancy parameters.

The HRMS data provide high-resolution mass spectra of the synthesized compounds.

The DLS data include measurements of the hydrodynamic diameters and zeta potentials of trans- and cis-AzoMUS@AuNPs.



Subject
Chemistry
Keyword

light-driven catalysis, gold nanoparticles, azobenzene photoswitch, confined reactions, monolayer compaction

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NMR.zip
ZIP Archive - 6.3 MB - Jun 12, 2026 - 0 Downloads
MD5: 02f1890864de10c684e9b2b84f26b059
License: CC0 Creative Commons Zero 1.0
The NMR data document the synthesis and characterization of the AzoMUS ligand, determination of the pKa of S+ in the absence and presence of trans-AzoMUS@AuNPs and cis-AzoMUS@AuNPs, analysis of ligand desorption following iodine treatment of AzoMUS@AuNPs, and investigation of the complexation of S2+ with both nanoparticle photoisomers.
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UV_VIS.zip
ZIP Archive - 4.5 MB - Jun 12, 2026 - 0 Downloads
MD5: a3e7f88ad448e9e4a30678145c87fd4b
License: CC0 Creative Commons Zero 1.0
The UV–Vis data include kinetic studies of S+-long and S2+ in the presence of trans- and cis-AzoMUS@AuNPs, determination of the binding constants of S2+ with both nanoparticle forms, stoichiometry analysis of S2+-AzoMUS@AuNP complexes using Job plots, evaluation of activation parameters through Arrhenius and Eyring analyses, and calculation of Hill-derived occupancy parameters.
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HRMS.zip
ZIP Archive - 485.5 KB - Jun 12, 2026 - 0 Downloads
MD5: 0327cb33b6d7b3d83b5ddf14614d7280
License: CC0 Creative Commons Zero 1.0
The HRMS data provide high-resolution mass spectra of the synthesized compounds.
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DLS.zip
ZIP Archive - 3.2 KB - Jun 12, 2026 - 0 Downloads
MD5: 6667614fff23bd08d521bbc03b34d63c
License: CC0 Creative Commons Zero 1.0
The DLS data include measurements of the hydrodynamic diameters and zeta potentials of trans- and cis-AzoMUS@AuNPs.
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TEM.zip
ZIP Archive - 6.9 MB - Jun 12, 2026 - 0 Downloads
MD5: 8acf6e93baa88fadf26d0bd6a3f80395
License: CC0 Creative Commons Zero 1.0
The TEM data provide images of small- and large-sized AzoMUS@AuNPs for morphological and size analyses.
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