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Hubkowska-Kosińska, Katarzyna, 2024, "The electrochemical and physicochemical properties of unmodified and Pd-NPs modified AB5 hydrogen storage alloy in selected protic and aprotic ionic liquids", https://doi.org/10.18150/RXZXFJ, RepOD, V2
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The data contains the results of the study of the electrochemical behavior of AB5 alloy and its composite with Pd nanoparticles in selected ionic liquids. The protic ionic liquid (diethylmethylammonium triflate) and the mixture of aprotic ionic liquid (1-ethyl-3-methylimidazolium methanesulfonate) with parent superacid were used as electrolytes in the process of hydrogen electrosorption in AB5 alloy electrodes. The impact of the surface modification of AB5 electrode with Pd nanoparticles has been checked. The studies revealed that the highest hydrogen absorption capacity can be obtained in Pd-NPs-AB5 electrode in DEMA-TFO. It was found that the surface modification with Pd-NPs facilitates the activation of the electrode and results in stabilization of the plateau potential of discharging. The studies show that more effort should be put into the synthesis of less corrosive tailored ionic liquids suitable to be used as electrolytes in hydride batteries.
AB5 alloy, ionic liquid, palladium nanoparticles, hydrogen sorption, 1-ethyl-3- methylimidazolium methanesulfonate, diethylmethylammonium triflate
Hubkowska, K.; Pająk, M.; Soszko, M.; Czerwiński, A. The Electrochemical Behavior of Unmodified and Pd-NPs Modified AB5 Hydrogen Storage Alloy in Selected Protic and Aprotic Ionic Liquids (ILs): Towards ILs-Based Electrolytes for Ni-MH Batteries. Molecules 2023, 28, 856. https://doi.org/10.3390/molecules28020856 https://doi.org/10.3390/molecules28020856 doi: 10.3390/molecules28020856
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