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Sołtys-Brzostek, Katarzyna; Terlecki, Michał; Lewiński, Janusz, 2025, "Adsorption Data for Activated WUT-1′(Ni) and WUT-2′(Ni) Materials", https://doi.org/10.18150/NAYLTJ, RepOD, V1
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This dataset contains adsorption isotherms for activated porous materials WUT-1′(Ni) and WUT-2′(Ni), derived from the removal of guest solvent molecules from WUT-1(Ni) and WUT-2(Ni), respectively. Both compounds are based on the same decanuclear nickel(II) hydroxyquinolinato-carbonato cluster, with the molecular formula [Ni10(μ6-CO3)4(L)12], where L = 2-hydroxyquinolinate. Depending on crystallization conditions, the clusters self-assemble into two distinct porous network topologies: diamondoid (WUT-1) or pyrite-type (WUT-2). The materials exhibit reversible phase transitions and selective gas separation properties. The dataset includes raw experimental adsorption isotherms in the Adsorption Information File (AIF) format for various gases and temperatures.
adsorption isotherms, porous materials, metal-organic frameworks, gas separation
K. Sołtys-Brzostek, K. Sokołowski, I. Justyniak, A. Li, D. Fairen-Jimenez, A. Supeł, M. Terlecki, J. Lewiński Tunable self-assembly of decanuclear Ni(II) carbonato clusters with hydroxyquinolinato shell: Robust porous networks with reversible solvent/temperature-driven phase transitions and selective gas separation Journal of the American Chemical Society, 2025, doi: 10.1021/jacs.5c04096 doi: 10.1021/jacs.5c04096
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