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Witkowski, Bartłomiej, 2023, "Kinetic dataset - aqueous oxidation of aliphatic molecules by hydroxyl radical", https://doi.org/10.18150/CPIWK1, RepOD, V1
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In the two spreadsheets included in this dataset, the values of the bimolecular reaction rate coefficients for the aqueous oxidation of aliphatic alcohols, diols, carboxylic acids (protonated forms), and carboxylate anions (deprotonated forms) are compiled. These data include the literature data (cited within the readme.txt file) and the values of bimolecular reaction rate coefficients that were measured as a part of the study described in the connected article. According to the Arrhenius relationship, the values of bimolecular reaction rate coefficients are temperature-dependent. In the first spreadsheet (Data_298K), the values of bimolecular reaction rate coefficients at 298K are included. In the second spreadsheet, (Data_all_temp) the values of bimolecular reaction rate coefficients in the temperature range between 278 and 328K are included.
kinetics, hydroxyl radicals, aqueous kinetics, atmospheric chemistry, structure-activity relationship, cloud water chemistry, secondary organic aerosols
Witkowski, B., Jain, P., Wileńska, B., and Gierczak, T.: Temperature-dependent aqueous OH kinetics of C2-C10 linear and terpenoid alcohols and diols: new rate coefficients, structure-activity relationship and atmospheric lifetimes, EGUsphere [preprint], 2023, doi: 10.5194/egusphere-2023-1381. https://doi.org/10.5194/egusphere-2023-1381 doi: 10.5194/egusphere-2023-1381
CC BY - Creative Commons Attribution 4.0
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