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Hubkowska-Kosińska, Katarzyna, 2024, "Pd-H as an irreplaceable model system for the study of hydrogen electrosorption in aqueous and non-aqueous electrolytes", https://doi.org/10.18150/B7LLRP, RepOD, V1
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Even though Pd-H system has been known since the 19th century, it is still of interest to scientists. Pd thin film electrode (called as a Limited Volume Electrode – LVE) is able to electrosorb hydrogen form aqueous (acid, base) and non-aqueous electrolytes (e.g. ionic liquids). Therefore Pd-H is an irreplaceable model system for the study of hydrogen electrosorption in different media. The paper presents: (1) short overview of the study of hydrogen sorption in Pd, (2) the detailed description of the electrochemical measurement methods and (3) the equations for the determination of hydrogen electrosorption charges needed to hydrogen electrosorption isotherms creation. The results show that Pd-LVE can be effectively used as a model system before the studies of multicomponent hydrogen storage alloys (e.g. AB5 alloys).
For further details, see files 'Data_description.odt' or 'Data_description.docx'.
hydrogen sorption, Pd-H system, α→β/β→α phase transition, non-aqueous electrolytes, ionic liquids
Hubkowska, K.; Pająk, M.; Soszko, M.; Czerwiński, A. The Electrochemical Behavior of Unmodified and Pd-NPs Modified AB5 Hydrogen Storage Alloy in Selected Protic and Aprotic Ionic Liquids (ILs): Towards ILs-Based Electrolytes for Ni-MH Batteries. Molecules 2023, 28, 856. https://www.mdpi.com/1420-3049/28/2/856 doi: 10.3390/molecules28020856
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