Publication raw data
File: Acidicy
File format: *txt
Data from pyridine adsorption measurements
FTIR spectrometer Invenio, Bruker, MCT detector; Opus Touch software;
spectra range 4000–600 cm−1; 100 scans; resolution 2 cm−1;
Samples were pressed into pellets at p = 3 bar. Activation of the sample: drying 200◦C;
Adsorption of pyridine vapors: 150◦C
Desorption: 150◦C
File:ASAP
File format: *xlsx; *csv
Data from nitrogen adsorption/desorption measurements
ASAP2020 Micromeritics; ASAP2020 software
Samples degassed at 200 ◦C under vacuum for 24 h. Nitrogen adsorption at −196◦C. The specific surface area calculated using Braunauer, Emmet and Teller (BET) equation, micropore size using the Dubinin–Astakhov equation.
File:FTIR
File format: *txt; *spa
Data from FTIR measurements
NICOLET 6700 spectrometer; Thermo Fisher Scientific; OMNIC software; KBr technique (pellet: 5% of sample in KBr);
Spectra range 650–4000 cm−1; resolution 4 cm−1.
File:Hg porosimetry
File format: *csv; *xlsx
Data from mercury porosimetry
Quantachrome Poremaster 33; PoroWin software;
pressure range 0.2–33,000 psi;
File:SEM EDX
File format:*tiff
Images from SEM
Phenom XL Thermo Fisher Scientific electron dispersive spectroscopy (EDS) system; Back-scattered electron detector (BSE);
acceleration voltage of 10 kV
Samples coated with 3 nm gold layer; EM ACE200 vacuum coater Leica
The EDS mapping: BSE detector; voltage 5 kV
File:UV-VIS
File format:*csv
Data from UV-Vis measurements
Varian Carry 100 spectrometer equipped with Labsphere DRACA-3300; Cary WinUV software;
spectra range 190-240 nm;
Samples calcined at 400 ◦C; 1 h prior measurements.
File:XPS
File format:*csv
Data from XPS measurements
PREVAC EA15 hemispherical electron energy analyzer; 2D-MCP detector; system base pressure 8 × 10−9 Pa; excitation energy 1486.60 eV; Al-Kα radiation PREVAC dual-anode XR-40B source; Measurements were made with a normal take-off angle. The binding energy scale calibrated to Au 4f7/2 (84.0 eV). The data elaboration: CASA XPS® algorithms; relative sensitivity factors; Shirley function was used for background subtraction. The particular components were fitted with a sum of Gaussian (70%) and Lorentzian (30%) lines. The uncertainty of determining the position of the energy 0.11 eV.
File:XRD
File format:*ASC; *pdf;*xrdml
Data from XRD measurements
Philips/Panalytical X’Pert ProMD powder diffractometer, Malvern Panalytical; Bragg–Brentano geometry; CuKα radiation
File: Catalytic Experiments
File format:*pdf
Reports from GC chromatography
Agilent 7890A, flame ionization detector FID; capillary column HP5; Inlet temperature: 250◦C ; sample volume: 1um, split ratio: 5:1; oven temp: 40◦C-200o◦C He flow 6.5 ml/min; detector: temperature 300◦C; H2 flow:30 ml/min, Air flow:400ml/min
